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Technology

Spotlight on Systems Research
Four universities strive to improve the way lighting systems, solar-harvesting technologies, and HVAC work
(archrecord.construction.com - June 2005)

By Ted Smalley Bowen

This diagram shows the design of a flexible solar cell containing a layer of “quantum dots” that harvest sunlight, pioneered by the University of Toronto.

Behind every technological breakthrough that grabs headlines are scores of smaller-scale studies aimed at improving the way existing products and systems work. Often, the innovations in product or system design that result from such studies are difficult to envision: Who could have guessed that the chunky blocks of plastic that passed for mobile phones 15 years ago would evolve into the multifunctional, slim-as-a-credit-card fashion accessories they are today? In this feature—really a series of four featurettes—we highlight research projects in energy efficiency that point the way toward substantial improvements in the way buildings use (or harvest) power. How about thin, flexible solar cells that can be ordered by the roll, like paper? Or using your laptop to dim the lights and turn off the air-conditioning in your office when you step out at lunchtime? The science behind these scenarios is there, even if all the technological details and cost issues haven’t been resolved yet. As energy prices remain uncertain, it’s likely that owners will have more incentives in the future to employ strategies that curtail energy usage, whether for retrofits or new construction. Imagining what form those solutions might take—as these researchers are doing—is half the fun. - Deborah Snoonian, P.E.

Tapping solar radiation’s unseen benefits

Most designers think of sunlight as a destructive force when it comes to surface treatments. They look for UV-stable paints and coatings, and calculate life-cycle costs with the expectation of regularly replacing exposed surfaces. But recent advances in materials science point to coverings—even paints and fabrics—that double as solar cells. Instead of worrying about the deleterious effects of the sun, designers could look forward to using a variety of building materials that have embedded energy-producing capacity.

Researchers at the University of Toronto, in Canada, have expanded the range of solar radiation that such materials can harvest, tapping infrared rays as well as the visible spectrum of light (current solar technology works in the visible spectrum only). This could boost the efficiency of new photovoltaic materials and make them more affordable; it also opens the way for cheap infrared cameras, which could figure in building-security systems.

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The researchers’ infrared-active colloidal “quantum dots” are made up of lead sulfur nanocrystals and semiconducting plastic. By changing the size of the nanocrystals, the researchers can “tune” the quantum dots to absorb wavelengths from 800 to 2,000 nanometers.

Within five years or so, architects and builders might be able to specify rolls of thin, lightweight, and flexible plastic solar sheeting, made by spraying a solvent containing the nanocrystals onto a thin, flexible substrate within a controlled manufacturing environment. Manufacturers might also choose to coat glass or metal surfaces with the solvent, according to lead researcher Ted Sargent, a University of Toronto professor of electrical and computer engineering. Applying the solvent like paint to such materials in the field won’t work, says Sargent, because the process needs to be carried out in a controlled, clean environment to be successful.

Lightweight and flexible solar cells would do away with many of the limitations of current silicon-based PV cells, which are heavy, breakable, bulky, and relatively expensive to install. The quantum dots could also be used to make thermal photovoltaic cells, tapping infrared radiation from fuel-fired sources, and for medical diagnostics, using infrared light to screen for cancer, according to the researchers.

The ability to harness infrared radiation could make solar energy more practical in more geographic areas, “assuming there’s some total power-production rate threshold that has to be met before the approach becomes economical in a given area,” Sargent said. “There is a mild advantage in that some infrared light makes it better through clouds, but the main point is that harvesting infrared as well as the visible wavelengths results in more power harvested.”

Traditional silicon-based solar panels (above) are often derided for being clunky and expensive. Researchers at Georgia Tech are making organic solar cells that are thin and flexible (below).
Photography: © Royalty-Free/CORBIS (top);
Courtesy Georgia Institute of Technology (bottom)

The quantum dots represent an early stage in the evolution toward commercially available solar cells. But their internal quantum efficiency—the amount of photons absorbed that actually reach the electrical circuit and are turned into usable energy—is just 3 percent, compared to 90 percent for most PV cells now on the market. The researchers are working on increasing this number, along with the quantum dots’ absorption of external light and their external power efficiency, or the ability to harvest the sun’s power efficiently over the entire spectrum, absorbing more light at multiple wavelengths and ensuring that the efficiencies are additive, Sargent said.

Researchers are also addressing the environmental trade-offs in making solar cells, a process that’s energy-intensive and involves hazardous chemicals. The lead sulfide nanoparticles in the Toronto study “need to be encapsulated, and an end-of-life strategy is needed, such as recycling of the materials,” Sargent said. He noted that the lead sulfide is “a showcase for the technology. The approach illustrates the value of infrared harvesting cheaply and flexibly. Once we or others develop even more innocuous materials that do the same thing, they will be adopted.”

Creating a process for making any material a solar collector by applying quantum dots is a step in the right direction, said Alexis Karolides, an architect and green-building consultant with the Rocky Mountain Institute. “Instead of asking how much can we increase the efficiency of current photovoltaic technology, we need to ask what’s possible,” she said.

Down the road, embedded solar cells and solar sheeting will need to be integrated with building control systems and power storage technologies like hydrogen fuel cells, according to Sargent. “Presumably, the days when the sun is shining don’t correspond identically with your power needs—so you might think of looking at power harvesting and storage problems together, in an integrated fashion.”

Going solar could mean going organic

Despite their advantages, there are many reasons to look for alternatives to existing silicon-based photovoltaic (PV) cells. Heavy, bulky, brittle, and aesthetically compromised, the older designs require clean-room manufacturing facilities, and are made using some less-than-clean materials and processes. Transportation and installation can also be expensive, resulting in higher capital costs.

Thin-film solar cells made of amorphous silicon and other materials address some of the drawbacks of current PV cells, including weight and flexibility—but some of these newer technologies raise environmental and safety questions of their own. More promising, but earlier in development, are organic solar cells, which have the potential to be relatively cheap, easier and cleaner to produce, and more versatile than existing solar technology.

Researchers at the Georgia Institute of Technology have developed a lightweight, flexible, organic photovoltaic cell using pentacene, a polycrystalline organic semiconductor, and the carbon molecule C60. Pentacene is often used in research on transistors, and C60 is in the family of carbon molecules commonly referred to as “buckyballs,” named for their resemblance to Buckminster Fuller’s designs.

The Georgia Tech organic solar cell consists of a glass plate, layers of indium oxide, pentacene, C60, and bathocuproine, and an aluminum electrode. According to lead researcher Bernard Kippelen, a professor of electrical and computer engineering at the university, it can be produced inexpensively...

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